Home » Countries Alphabetical » 2 Countries That Start with the Letter “Z” 2 Countries That Start with the Letter “Z” There are two countries that start with the letter “Z”. #Country NameEmoji FlagUN NationAlpha 3 CodePopulation (2022)Continent 1ZambiaπΏπ²YesZMB20,017,675Africa 2ZimbabweπΏπΌYesZWE16,320,537Africa Countries with “Z” on the World Map